2001/59/EC Risk and Safety Statements
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Risk and Safety Statements
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European Union Commission Directive 2001/59/EC defines hazard codes and phrases
for classification, packaging and labeling of dangerous substances.
For complete hazard and safety information always refer to the MSDS.
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RISK AND SAFETY STATEMENTS
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For your convenience Sigma's labels include Risk and Safety numbers.
Please refer to the following table for the respective Risk and Safety Statements
for these numbers and combinations of numbers. In addition, Fluka Brand products contain F codes to assist with Risk and Safety information. Fluka F codes are also outlined below.
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Risk Phrases
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Safety Precautions
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______________________________________________________________________
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Indication of Particular Risks
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R1:
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Explosive when dry
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2:
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Risk of explosion by shock, friction, fire or other sources of ignition
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3:
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Extreme risk of explosion by shock, friction, fire or other sources of ignition
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4:
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Forms very sensitive explosive metallic compounds
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5:
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Heating may cause an explosion
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6:
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Explosive with or without contact with air
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7:
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May cause fire
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8:
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Contact with combustible material may cause fire
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9:
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Explosive when mixed with combustible material
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10:
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Flammable
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11:
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Highly Flammable
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12:
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Extremely Flammable
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14:
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Reacts violently with water
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15:
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Contact with water liberates extremely flammable gases
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16:
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Explosive when mixed with oxidizing substances
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17:
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Spontaneously flammable in air
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18:
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In use may form flammable/explosive vapor-air mixture
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19:
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May form explosive peroxides
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20:
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Harmful by inhalation
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21:
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Harmful in contact with skin
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22:
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Harmful if swallowed
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23:
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Toxic by inhalation
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24:
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Toxic in contact with skin
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25:
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Toxic if swallowed
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26:
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Very Toxic by inhalation
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27:
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Very Toxic in contact with skin
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28:
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Very Toxic if swallowed
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29:
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Contact with water liberates toxic gas
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30:
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Can become highly flammable in use
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31:
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Contact with acids liberates toxic gas
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32:
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Contact with acids liberates very toxic gas
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33:
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Danger of cumulative effects
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34:
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Causes burns
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35:
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Causes severe burns
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36:
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Irritating to the eyes
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37:
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Irritating to the respiratory system
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38:
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Irritating to the skin
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39:
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Danger of very serious irreversible effects
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40:
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Limited evidence of a carcinogenic effect
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41:
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Risk of serious damage to eyes
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42:
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May cause sensitization by inhalation
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43:
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May cause sensitization by skin contact
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44:
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Risk of explosion if heated under confinement
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45:
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May cause cancer
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46:
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May cause heritable genetic damage
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48:
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Danger of serious damage to health by prolonged exposure
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49:
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May cause cancer by inhalation
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50:
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Very Toxic to aquatic organisms
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51:
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Toxic to aquatic organisms
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52:
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Harmful to aquatic organisms
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53:
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May cause long-term adverse effects in the aquatic environment
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54:
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Toxic to flora
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55:
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Toxic to fauna
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56:
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Toxic to soil organisms
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57:
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Toxic to bees
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58:
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May cause long-term adverse effects in the environment
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59:
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Dangerous for the ozone layer
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60:
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May impair fertility
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61:
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May cause harm to the unborn child
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62:
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Possible risk of impaired fertility
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63:
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Possible risk of harm to the unborn child
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64:
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May cause harm to breast-fed babies
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65:
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Harmful: May cause lung damage if swallowed
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66:
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Repeated exposure may cause skin dryness or cracking
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67:
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Vapors may cause drowsiness and dizziness
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68:
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Possible risk of irreversible effects
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Combination of Particular Risks
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14/15:
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Reacts violently with water, liberating extremely flammable gases
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15/29:
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Contact with water liberates toxic, extremely flammable gas
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20/21:
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Harmful by inhalation and in contact with skin
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20/21/22:
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Harmful by inhalation, in contact with skin and if swallowed
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20/22:
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Harmful by inhalation and if swallowed
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21/22:
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Harmful in contact with skin and if swallowed
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23/24:
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Toxic by inhalation and in contact with skin
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23/24/25:
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Toxic by inhalation, in contact with skin and if swallowed
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23/25:
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Toxic by inhalation and if swallowed
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24/25:
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Toxic in contact with skin and if swallowed
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26/27:
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Very Toxic by inhalation and in contact with skin
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26/27/28:
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Very Toxic by inhalation, in contact with skin and if swallowed
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26/28:
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Very Toxic by inhalation and if swallowed
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27/28:
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Very Toxic in contact with skin and if swallowed
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36/37:
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Irritating to eyes and respiratory system
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36/37/38:
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Irritating to eyes, respiratory system and skin
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36/38:
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Irritating to eyes and skin
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37/38:
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Irritating to respiratory system and skin
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39/23:
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Toxic: danger of very serious irreversible effects through inhalation
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39/23/24:
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Toxic: danger of very serious irreversible effects through inhalation in contact with skin
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39/23/24/25:
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Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
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39/23/25:
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Toxic: danger of very serious irreversible effects through inhalation and if swallowed
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39/24:
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Toxic: danger of very serious irreversible effects in contact with skin
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39/24/25:
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Toxic: danger of very serious irreversible effects in contact with skin and if swallowed
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39/25:
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Toxic: danger of very serious irreversible effects if swallowed
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39/26:
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Very Toxic: danger of very serious irreversible effects through inhalation
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39/26/27:
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Very Toxic: danger of very serious irreversible effects through inhalation and in contact with skin
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39/26/27/28:
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Very Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
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39/26/28:
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Very Toxic: danger of very serious irreversible effects through inhalation and if swallowed
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39/27:
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Very Toxic: danger of very serious irreversible effects in contact with skin
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39/27/28:
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Very Toxic: danger of very serious irreversible effects in contact with skin and if swallowed
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39/28:
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Very Toxic: danger of very serious irreversible effects if swallowed
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42/43:
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May cause sensitization by inhalation and skin contact
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48/20:
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Harmful: danger of serious damage to health by prolonged exposure through inhalation
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48/20/21:
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Harmful: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin
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48/20/21/22:
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Harmful: danger of serious damage to health by prolonged exposure through inhalation, and in contact with skin and if swallowed
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48/20/22:
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Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed
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48/21:
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Harmful: danger of serious damage to health by prolonged exposure in contact with skin
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48/21/22:
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Harmful: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed
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48/22:
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Harmful: danger of serious damage to health by prolonged exposure if swallowed
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48/23:
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Toxic: danger of serious damage to health by prolonged exposure through inhalation
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48/23/24:
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Toxic: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin
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48/23/24/25:
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Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed
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48/23/25:
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Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed
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48/24:
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Toxic: danger of serious damage to health by prolonged exposure in contact with skin
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48/24/25:
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Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed
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48/25:
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Toxic: danger of serious damage to health by prolonged exposure if swallowed
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50/53:
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Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
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51/53:
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Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
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52/53:
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Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
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68/20:
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Harmful: possible risk of irreversible effects through inhalation
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68/20/21:
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Harmful: possible risk of irreversible effects through inhalation and in contact with skin
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68/20/21/22:
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Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed
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68/20/22:
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Harmful: possible risk of irreversible effects through inhalation and if swallowed
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68/22:
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Harmful: possible risk of irreversible effects if swallowed
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68/21:
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Harmful: possible risk of irreversible effects in contact with skin
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68/21/22:
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Harmful: possible risk of irreversible effects in contact with skin and if swallowed
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68/22:
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Harmful: possible risk of irreversible effects if swallowed
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Indication of Safety Precautions
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S1:
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Keep locked up
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2:
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Keep out of the reach of children
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3:
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Keep in a cool place
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4:
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Keep away from living quarters
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5:
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Keep contents under ... (appropriate liquid to be specified by the manufacturer)
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6:
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Keep under ... (inert gas to be specified by the manufacturer)
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7:
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Keep container tightly closed
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8:
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Keep container dry
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9:
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Keep container in a well-ventilated place
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12:
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Do not keep the container sealed
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13:
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Keep away from food, drink and animal feeding stuffs
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14:
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Keep away from ... (incompatible materials to be indicated by the manufacturer)
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15:
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Keep away from heat
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16:
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Keep away from sources of ignition - No smoking
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17:
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Keep away from combustible material
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18:
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Handle and open container with care
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20:
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When using, do not eat or drink
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21:
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When using, do not smoke
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22:
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Do not breathe dust
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23:
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Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer)
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24:
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Avoid contact with skin
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25:
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Avoid contact with eyes
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26:
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In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
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27:
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Take off immediately all contaminated clothing
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28:
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After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)
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29:
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Do not empty into drains
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30:
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Never add water to this product
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33:
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Take precautionary measures against static discharges
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35:
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This material and its container must be disposed of in a safe way
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36:
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Wear suitable protective clothing
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37:
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Wear suitable gloves
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38:
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In case of insufficient ventilation, wear suitable respiratory equipment
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39:
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Wear eye/face protection
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40:
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To clean the floor and all objects contaminated by this material use ... (to be specified by the manufacturer)
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41:
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In case of fire and/or explosion do not breathe fumes
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42:
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During fumigation/spraying wear suitable respiratory equipment (appropriate wording to be specified)
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43:
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In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
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45:
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In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
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46:
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If swallowed, seek medical advice immediately and show this container or label
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47:
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Keep at temperature not exceeding ... E C (to be specified by the manufacturer)
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48:
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Keep wetted with ... (appropriate material to be specified by the manufacturer)
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49:
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Keep only in the original container
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50:
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Do not mix with ... (to be specified by the manufacturer)
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51:
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Use only in well-ventilated areas
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52:
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Not recommended for interior use on large surface areas
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53:
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Avoid exposure - obtain special instruction before use
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56:
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Dispose of this material and its container to hazardous or special waste collection point
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57:
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Use appropriate container to avoid environmental contamination
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59:
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Refer to manufacturer/supplier for information on recovery/recycling
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60:
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This material and/or its container must be disposed of as hazardous waste
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61:
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Avoid release to the environment. Refer to special instructions safety data sheet
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62:
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If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label
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63:
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In case of accident by inhalation, remove casualty to fresh air and keep at rest
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64:
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If swallowed, rinse mouth with water (only if the person is conscious)
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Combination of Safety Precautions
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1/2:
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Keep locked up and out of the reach of children
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3/7:
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Keep container tightly closed in a cool place
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3/9/14:
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Keep in a cool well-ventilated place away from ... (incompatible materials to be indicated by manufacturer)
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3/9/14/49:
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Keep only in the original container in a cool well-ventilated place away from ... (incompatible materials to be indicated by manufacturer)
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3/9/49:
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Keep only in the original container in a cool well-ventilated place
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3/14:
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Keep in a cool place away from ... (incompatible materials to be indicated by the manufacturer)
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7/8:
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Keep container tightly closed and dry
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7/9:
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Keep container tightly closed and in a well-ventilated place
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7/47:
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Keep container tightly closed and at a temperature not exceeding ... °C (to be specified by manufacturer)
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20/21:
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When using, do not eat, drink or smoke
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24/25:
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Avoid contact with skin and eyes
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27/28:
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After contact with skin, take off immediately all contaminated clothing and wash imediately with plenty of.... (to be specified by the manufacturer)
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29/35:
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Do not empty into drains, dispose of this container and it's material in a safe way
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29/56:
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Do not empty into drains, dispose of this material and its container to hazardous or special waste-collection point
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36/37:
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Wear suitable protective clothing and gloves
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36/37/39:
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Wear suitable protective clothing, gloves and eye/face protection
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36/39:
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Wear suitable protective clothing and eye/face protection
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37/39:
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Wear suitable gloves and eye/face protection
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47/49:
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Keep only in the original container at temperature not exceeding ... °C (to be specified by manufacturer)
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F 1 Sensitive to air and humidity.
F 2 Sensitive to air and CO2.
F 3 Hygroscopic.
F 4 Do not heat over …°C.
1 = 10 °C
2 = 20 °C
3 = 30 °C
4 = 40 °C
5 = 50 °C
6 = 60 °C
7 = 70 °C
8 = 80 °C
9 = 90 °C
10 = 100 °C
11 = 110 °C
12 = 120 °C
13 = 130 °C
14 = 140 °C
15 = 150 °C
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F 5 Dry material may explode.
F 6 Reacts with acids.
F 7 Keep under CO2.
F 8 Photosensitive.
F 9 Keep under nitrogen.
F 10 Keep under argon.
F 11 Keep under inert gas.
F 12 Shake before use.
F 13 Malodorous.
F 14 Carefully observe warning label.
F 15 Limited shelf life.
F 16 Decomposes easily.
F 17 May decompose by explosion.
F 18 Must be handled by instructed people only.
F 19 Lachrymator.
F 20 Not to be swallowed.
F 21 Sensitive to humidity.
F 22 Keep dust-free in the dark.
F 23 Sensitive to air.
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F 24 Spontaneously flammable with alcohol.
F 25 Keep under CO.
F 26 Before distillation test for absence of peroxides.
F 27 Cool before opening.
F 28 May become cloudy (Polyformaldehyde).
F 29 Spontaneously flammable when dry.
F 30 Sediment unavoidable.
F 31 Do not puncture.
F 32 Avoid contact with heavy metal salts
especially iron salts.
F 33 Causes fall in blood pressure.
F 34 Sensitive to CO2.
F 35 Narcotic effects.
F 36 Extremely sensitive to air.
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PICTOGRAMS AND HAZARD CODES
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B
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Biohazard
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F
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Highly Flammable
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F+
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Extremely Flammable
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O
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Oxidizing
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C
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Corrosive
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R
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Radioactive
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E
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Explosive
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N
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Dangerous for the
environment
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亿博检测高级技术顾问certified engineer
何婷婷 2015年进入亿博检测技术有限公司，担任高级销售顾问。
精通各类检测认证标准，服务过上千家企业。 联系方式：13570847473（微信同号） 座机：0755-33126673 传真：0755-22639141
邮箱：kefu@ebotek.cn
地址：深圳市宝安新安六路勤业商务中心A栋一楼112-114
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